Synthesis and Terminal Functionalization of Ethylene-Propylene Copolymers Obtained with Et(H4Ind)2ZrCl2-methylalmoxane Catalyst.

Synthesis and Saxs Characterization of Sulfonated Styrene-ethylene/propylene-styrene Triblock Copolymers

On the Configurational Statistics of Ethylene-Propylene Copolymers

Mean-square unperturbed dimensions {r2)0 and their temperature coefficient d In{r2)0/dT have been calculated for ethylene-propylene copolymers by means of the rotational isomeric state theory of chain molecules. Conformational energies required in the analysis are shown to be readily obtained from previous analyses of polyethylene and polypropylene, without additional approximations. Results th...

Quantification of identical and unique segments in ethylene-propylene copolymers using two dimensional liquid chromatography with infra-red detection

Hyphenating High Temperature High Performance Liquid Chromatography (HT-HPLC) with High Temperature Size Exclusion Chromatography (HT-SEC) (High Temperature Two Dimensional Liquid Chromatography (HT-HPLC x HT-SEC or HT 2D-LC)) leads to an isocratic elution in the second dimension, which in turn enables to use IR detector (quantitative detection) for monitoring the eluting polymers. Experimental...

synthesis of (ind)2zrcl2 catalyst for copolymerization of ethylene and propylene: parameters effect on productivity

bis(indenyl)zirconium dichloride as a catalyst was synthesized using a modified method at the room temperature. polymerization of ethylene and copolymerization of ethylene and propylene were carried out by this metallocene catalyst. ethylene propylene (p/e) feed ratios of 0.25, 0.5, 1, and 2 were employed into the copolymerization systems. copolymerization conditions like cocatalyst/catalyst ra...

Synthesis of Ethylene or Propylene/1,3-Butadiene Copolymers Possessing Pendant Vinyl Groups with Virtually No Internal Olefins

In general, ethylene/1,3-butadiene copolymerizations provides copolymers possessing both pendant vinyls and vinylenes as olefinic moieties. We, at MCI, studied the substituent effects of C2-symmetric zirconocene complexes, rac-[Me2Si(Indenyl’)2]ZrCl2 (Indenyl’ = generic substituted indenyl), after activation on the ratio of the pendant vinyls and vinylenes of the resultant copolymers. Complexes...